کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
10567331 972641 2005 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Association interaction and voltammetric determination of 1-aminopyrene and 1-hydroxypyrene at cyclodextrin and DNA based electrochemical sensors
موضوعات مرتبط
مهندسی و علوم پایه شیمی الکتروشیمی
پیش نمایش صفحه اول مقاله
Association interaction and voltammetric determination of 1-aminopyrene and 1-hydroxypyrene at cyclodextrin and DNA based electrochemical sensors
چکیده انگلیسی
The aim of this work was voltammetric determination of 1-aminopyrene and 1-hydroxypyrene using carbon paste electrodes modified with cyclodextrin derivatives and double stranded deoxyribonucleic acid (dsDNA). The detection schemes based on a preconcentration and differential pulse voltammetric (DPV) determination at β-cyclodextrin and γ-cyclodextrin modified carbon paste electrode (β-CD/CPE, γ-CD/CPE), neutral β-cyclodextrin polymer and carboxymethyl-β-cyclodextrin polymer modified screen-printed electrode (β-CDP/SPE, β-CDPA/SPE) and dsDNA modified screen-printed electrode (DNA/SPE) are proposed for the trace determination of studied analytes within the concentration range from 2×10−8 to 4×10−7 mol dm−3 and from 2×10−7 to 4×10−6 mol dm−3 with the limits of quantification down to 10−8 mol dm−3. Depending on pH, 1-aminopyrene interacts with both surface attached CD and DNA by electrostatic bonds and supramolecular complexation while 1-hydroxypyrene associates with the CD hosts via complexation. The 1-aminopyrene interaction with dsDNA was confirmed by fluorimetric measurements in the solution phase using a competing DNA-TO-PRO-3 dye complex. In addition, the effect of temperature on this association was investigated using an electrically heated DNA-modified carbon paste electrode (DNA/CPE).
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Bioelectrochemistry - Volume 67, Issue 2, October 2005, Pages 191-197
نویسندگان
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