Assembly of 1D, 2D and 3D silver(I) coordination polymers with nitrilotriacetate and 2-aminopyrimidyl mixed ligands

► Three mixed ligands silver(I) coordination polymers were synthesized and characterized. ► The structures of these complexes were confirmed by X-ray crystallography. ► Substituents on the 2-aminopyrimidine play a crucial role in the self-assembly. ► The photoluminescent properties of them were also investigated.