Diamidato-bis(diphenylphosphino) platinum(II) complexes: Synthesis, characterization, and reactivity in the presence of acid

► Synthesis of tetradentate diamidato-bis(phosphino) Pt(II) complexes. ► Solution (NMR) and solid state (X-ray) characterization of Pt(II)-Trost complexes. ► Temperature and pH dependent coordination versatility of Trost ligand complexes.