کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10571719 | 975182 | 2005 | 11 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis, characterization and X-ray structure of several aryloxide and alkoxide derivatives of [Et4N][Re2(CO)6(OR)3] (RÂ =Â H or Me)
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Synthesis, characterization and X-ray structure of several aryloxide and alkoxide derivatives of [Et4N][Re2(CO)6(OR)3] (RÂ =Â H or Me) Synthesis, characterization and X-ray structure of several aryloxide and alkoxide derivatives of [Et4N][Re2(CO)6(OR)3] (RÂ =Â H or Me)](/preview/png/10571719.png)
چکیده انگلیسی
We report on the ligand exchange reaction of [Et4N][Re2(CO)6(OR)3] with substituted aryl alcohols and with ethylene glycol. Complete exchange is fast with the alkyl alcohol but for the aryl alcohols exchange is facile only for two substitutions, the third substitution can be forced by raising the reaction temperature. X-ray crystal determinations were carried out for several of the derivatives.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Volume 358, Issue 4, 1 March 2005, Pages 1050-1060
Journal: Inorganica Chimica Acta - Volume 358, Issue 4, 1 March 2005, Pages 1050-1060
نویسندگان
Kevin K. Klausmeyer, Franklin R. Beckles,