کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
10572177 975290 2011 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
The first monoribbed-functionalized tris-dioximate iron(II) clathrochelate with two inherent NH2-substituents, its reactivity, acid-base and coordination-chemical properties
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
The first monoribbed-functionalized tris-dioximate iron(II) clathrochelate with two inherent NH2-substituents, its reactivity, acid-base and coordination-chemical properties
چکیده انگلیسی
► The iron(II) clathrochelate with two inherent NH2-groups was obtained. ► Clathrochelate NH2-groups have an amide character and undergo deprotonation. ► The clathrochelate dianion is an acido-ligand and coordinates to copper(II) ion. ► The condensation of clathrochelate dianion with benzil gave piperazinone fragment. ► The reaction is benzilic-type rearrangement with 1,2-shift of the phenyl substituent.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Volume 366, Issue 1, 30 January 2011, Pages 91-97
نویسندگان
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