کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
10575071 977331 2005 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Solubility of trans-Co2(CO)6 [3,5-bis(CF3)C6H3P(i-C3H7)2] in dense carbon dioxide
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Solubility of trans-Co2(CO)6 [3,5-bis(CF3)C6H3P(i-C3H7)2] in dense carbon dioxide
چکیده انگلیسی
The title compound (1) was prepared by the reaction of 3,5-bis(CF3)C6H3P(i-C3H7)2 (L1) and Co2(CO)8. Its solubility in supercritical carbon dioxide was measured at varying temperatures and pressures using a modified analytical extraction device. Solubility data were determined in the temperature and pressure ranges between 40 and 70 °C and between 100 and 300 bar, respectively. The solubility of 1 is lower compared to (p-CF3C6H4)3P, but much higher than for transition metal complexes bearing phosphines without fluorinated substituents.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 690, Issue 6, 15 March 2005, Pages 1467-1473
نویسندگان
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