کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10575092 | 977331 | 2005 | 11 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Reactivity and electrochemical behavior of ruthenium dithiolene complexes with coordinatively unsaturated metal centers: cycloaddition and dimerization reactions
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Reactivity and electrochemical behavior of ruthenium dithiolene complexes with coordinatively unsaturated metal centers: cycloaddition and dimerization reactions Reactivity and electrochemical behavior of ruthenium dithiolene complexes with coordinatively unsaturated metal centers: cycloaddition and dimerization reactions](/preview/png/10575092.png)
چکیده انگلیسی
The ruthenium dithiolene complex [(C6H6)Ru{S2C2(COOMe)2}] (1a) coexisted with the corresponding dimer [(C6H6)Ru{S2C2(COOMe)2}]2 (1aâ²) in solution, and complex 1a reacted with acetylenes or diazo compounds to give the alkene-bridged adducts [(C6H6)Ru{S2C2(COOMe)2}{C2(COOR)2}] (RÂ =Â Me (2a), Et (3a)) or the alkylidene-bridged adducts [(C6H6)Ru{S2C2(COOMe)2}(CHR)] (RÂ =Â H (4a), SiMe3 (5a), COOEt (6a)). The oxidant of complex 1a was immediately converted to the corresponding cationic dimer 1aâ²+, and the neutral complex 1a was regenerated when it was re-reduced.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 690, Issue 6, 15 March 2005, Pages 1627-1637
Journal: Journal of Organometallic Chemistry - Volume 690, Issue 6, 15 March 2005, Pages 1627-1637
نویسندگان
Mitsushiro Nomura, Mari Fujii, Katsura Fukuda, Toru Sugiyama, Yasuo Yokoyama, Masatsugu Kajitani,