کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
10575211 977348 2005 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A study of molybdenum catalysts in the polymerization of 2,5-didodecyl-1,4-dipropynylbenzene
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
A study of molybdenum catalysts in the polymerization of 2,5-didodecyl-1,4-dipropynylbenzene
چکیده انگلیسی
Investigation of molybdenum-based in situ catalyst systems for alkyne metathesis. The treatment of dipropynyldidodecylbenzene with a mixture of (acac)2MoO2 in the presence of 7 equivalents of triethylaluminum and 2-fluorophenol furnishes didodecyl-PPE of high molecular weight at temperatures as low as 105 °C in boiling toluene. A series of other molybdenum carbonyl complexes in the presence of phenols were as well investigated as metathesis catalysts. While all of the investigated catalyst precursors were active in the formation of PPEs, they are not more active than the original Mo(CO)6-4-chlorophenol system. The exception is the (acac)2MoO2-based catalyst that is significantly more active than all of the other investigated in situ catalyst systems.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 690, Issue 3, 28 January 2005, Pages 825-829
نویسندگان
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