کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10603354 | 982474 | 2013 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
On the weak dependence of water diffusivity on the degree of hydrophobicity of acetylated hydroxypropyl xylan
ترجمه فارسی عنوان
بر میزان وابستگی ضعیف آب به میزان هیدروفوبیت هیدروکسی پروپیل کایلین آتیلین
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
چکیده انگلیسی
The simulation results showed that the diffusivity of water at low concentrations in the chemically modified xylans decreased slightly (â¼20%) from HPX to APX with 3 acetylated hydroxyl moieties, a trend that has been experimentally observed for xylans and other cellulosic type materials. Further data analysis shows that acetylation decreases the ability of the xylan to form hydrogen bonds with water and its degree of swelling. And these two factors exert opposite effects on the diffusivity of water. In particular, the first factor increases the mobility (lower activation energy) of the water molecules, while the second factor reduces the free volumes available for diffusion, thereby decreasing the water mobility. This finding implies that it is not likely to obtain orders of magnitude change to the water diffusivity simply by the acetylation of all hydroxyl moieties on xylan. The high degree of swelling observed for HPX compared to those of APXs is attributed to the fact that many hydrogen bonds in HPX are broken by water. It is interesting to note that water in most of the hydrogen bonds formed between water and xylans acted as hydrogen bond acceptors rather than donors.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Carbohydrate Polymers - Volume 98, Issue 1, 15 October 2013, Pages 644-649
Journal: Carbohydrate Polymers - Volume 98, Issue 1, 15 October 2013, Pages 644-649
نویسندگان
Diwen Zhou, Fatemeh Bayati, Phillip Choi,