کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10610455 | 985916 | 2012 | 13 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Structural/textural properties and water reactivity of fluorinated activated carbons
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی انرژی
انرژی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Hydrophobic activated carbons are considered as interesting materials for air or water remediation due to their enhanced affinity for slightly water-soluble organic species. In this context, a commercial activated carbon, in an extruded form, was fluorinated under mild conditions (pure fluorine gas at room temperature) in order to decrease its hydrophilic character and to preserve its microporosity. For comparison, a hydrogenated activated carbon was also prepared by H2 treatment. The resulting samples were characterised by various techniques in order to determine the evolution of the activated carbon materials in terms of composition (XPS, elemental analysis, TGA and NMR) and porosity (nitrogen physisorption (77Â K), mercury intrusion and immersion calorimetry). For the fluorinated carbon, the nature of the CFx groups and the strength of the C-F bonds were also investigated using 13C and 19F solid state NMR and TGA techniques. A labile character of the C-F bond, so far exclusively observed for fluorine intercalation compounds, is also shown for the first time for a fluorinated activated carbon by water adsorption/desorption isotherms at room temperature. Care should then be taken for its use in presence of water.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Carbon - Volume 50, Issue 14, November 2012, Pages 5135-5147
Journal: Carbon - Volume 50, Issue 14, November 2012, Pages 5135-5147
نویسندگان
Julien Parmentier, Sébastien Schlienger, Marc Dubois, Elodie Disa, Francis Masin, Teresa A. Centeno,