کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10624907 | 989612 | 2014 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Grain size independence of giant dielectric permittivity of CaCu3Ti4âxScxO12 ceramics
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The dielectric and electrical properties of CaCu3Ti4âxScxO12 (x=0, 0.04, 0.08, and 0.20) ceramics prepared by a solid-state reaction method were investigated. Grain sizes of CaCu3Ti4O12 were greatly reduced by doping with Sc3+. Surprisingly, the dielectric constant of CaCu3Ti4âxScxO12 ceramics with x=0â0.08 largely increased as the mean grain size decreased. This behavior was extremely hard to produce in CaCu3Ti4O12 ceramics. The nonlinear currentâvoltage properties CaCu3Ti4âxScxO12 ceramics were significantly degraded. The grain boundary (GB) resistance decreased with increasing Sc3+ concentration even though the density of GB layer increased. This resulted in enhancement of a low-frequency loss tangent due to increased dc conduction. Substitution of some Sc3+ ions into Cu sites was proposed as the cause of reduction of the potential barrier height at GBs. The possible mechanisms of giant dielectric response in CaCu3Ti4O12 ceramics are discussed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Ceramics International - Volume 40, Issue 10, Part A, December 2014, Pages 15897-15906
Journal: Ceramics International - Volume 40, Issue 10, Part A, December 2014, Pages 15897-15906
نویسندگان
Keerati Meeporn, Teerapon Yamwong, Supree Pinitsoontorn, Vittaya Amornkitbamrung, Prasit Thongbai,