کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10638661 | 995428 | 2005 | 11 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
The effect of varying synthesis conditions on zinc chromium hydrotalcite: a spectroscopic study
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
مواد الکترونیکی، نوری و مغناطیسی
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چکیده انگلیسی
Zn/Cr hydrotalcites were synthesised by coprecipitation, with varying pH values and divalent/trivalent metal ion ratio. Depending on the pH conditions, two 3R rhombohedral varieties were synthesised with different layer spacings of 7.8 and 8.9Â Ã
, at room temperature. More carbonate was incorporated in the interlayer of samples prepared at low pH values, increasing the interlayer distance and the unit cell. Preparation under acidic conditions lead to a more crystalline, pure and thermally stable compound. Spectroscopy was used to determine the effect of varying the ratio of divalent/trivalent metal ion ratio. It was shown that although ratios >2 yield crystalline compounds a ratio of 3 was preferred for both phases.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Chemistry and Physics - Volume 89, Issue 1, 15 January 2005, Pages 99-109
Journal: Materials Chemistry and Physics - Volume 89, Issue 1, 15 January 2005, Pages 99-109
نویسندگان
J. Theo Kloprogge, Leisel Hickey, Ray L. Frost,