کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
11006445 | 1503030 | 2018 | 16 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Innovative high flux/low pressure blend thin film composite membranes for water softening
ترجمه فارسی عنوان
غشای کامپوزیت فیلم نازک نوآورانه شار / کم مخلوط برای نرم کردن آب
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کلمات کلیدی
مخلوط غشاء، پلیمریزاسیون اینترفیس بهینه سازی لایه پلی آمید، نانوفیلتراسیون، نرم کننده آب
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
چکیده انگلیسی
Nanofiltration (NF) thin film composite membranes were prepared via interfacial polymerization using piperazine with isophthaloyl chloride on porous PES/PAN blend membrane. The prepared membranes were characterized through chemical structure, morphology, surface charge studies and separation performance. All the variables are taken into consideration including reactive monomers amount. The monomers ratio were 1: 0.3: 0.3: 0.3 that corresponds to piperazine: sodium hydroxide: dodecyl sodium sulfate: isophthaloyl dichloride respectively. Soaking time for amine solution was 30â¯min, while it was 10â¯min in organic chloride solution. After interfacial polymerization the membranes have been annealed at temperature 80â¯Â°C for curing time 10â¯min. These were the optimum conditions which greatly enhanced the flux and the salt rejection of NF thin film composite membranes. The membranes have rejection percent in the order of 99.9, 99, 82, and 72% for Na2SO4, MgSO4, CaCl2, NaCl respectively without reducing water productivity. This study offers separation of 7000â¯ppm salt solution with low operating pressure (5 bars) compared with previous studies. The fabricated membranes were applied for 30â¯days with steady-state flux keeping their polyamide layers. As well; the fabricated membrane with the optimum operating conditions has a better fouling resistance for humic acid and molecular weight cut off 600â¯Da.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Reactive and Functional Polymers - Volume 131, October 2018, Pages 384-399
Journal: Reactive and Functional Polymers - Volume 131, October 2018, Pages 384-399
نویسندگان
Tarek S. Jamil, Eman S. Mansor, Heba Abdallah, A.M. Shaban,