کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
11015756 | 1781703 | 2019 | 24 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Yttrium modified Ni-rich LiNi0.8Co0.1Mn0.1O2 with enhanced electrochemical performance as high energy density cathode material at 4.5â¯V high voltage
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
This work adopts an effective method to stabilize the structure of Ni-rich LiNi0.8Co0.1Mn0.1O2 with yttrium modifying. The results of XRD, EDS, HR-TEM and XPS tests verify that the yttrium modified materials integrate surface nanoscale LiYO2 coating and inner gradient Y3+ doping. TGA and DSC tests confirm that yttrium modification can promote the thermal stability of LiNi0.8Co0.1Mn0.1O2 cathode material. The results of galvanostatic charge-discharge tests suggest that the 2â¯mol% yttrium modified sample can exhibit a superior cycling performance with initial discharge capacity of 189.4â¯mAh gâ1 and outstanding capacity retention of 98.4% after 100 cycles at 2.8-4.5â¯V, which presents obvious enhancement compared with the 83.5% capacity retention of pristine sample. The cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) tests indicate that 2â¯mol % yttrium modifying significantly enhances the diffusion of Li+ ions (DLi+) and notably decreases the electrochemical polarization of electrodes. The surface Li-ion conductor LiYO2 coating layer as a surface protector inhibits the side reaction and the gradient Y3+ doping supports the crystal structure, which can show synergistic effect in enhancing the electrochemical performance of LiNi0.8Co0.1Mn0.1O2 cathode material.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 774, 5 February 2019, Pages 82-92
Journal: Journal of Alloys and Compounds - Volume 774, 5 February 2019, Pages 82-92
نویسندگان
Meiling Zhang, Hongyuan Zhao, Ming Tan, Jintao Liu, Youzuo Hu, Shanshan Liu, Xiaohui Shu, Hao Li, Qiwen Ran, Jingjing Cai, Xingquan Liu,