کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
11016652 | 1774266 | 2019 | 29 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Ultra-efficient removal of NO in a MOFs-NTP synergistic process at ambient temperature
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
In this work, a new MOFs-NTP synergistic method was first proposed in order to study the denitration performance. As a highly efficient MOFs material, CuBTC was synthesized by microwave method and combined with non-thermal plasma (NTP) which achieved an ultra-efficiency of 97.87% for NO removal. It was 76.77% and 64.43% higher than that of the CuBTC-alone process and NTP-alone denitration process. The influential factors and characterization analysis (SEM, XRD, N2 adsorption-desorption isotherms, ESR, XPS) were also investigated to study the synergistic effect of the MOFs-NTP denitration process. The results showed that CuBTC could be activated by NTP and generated the coordinatively unsaturated Cu(I)/Cu(II) sites which greatly enhanced the surface catalytic activity of CuBTC. NO was mainly reduced by Cu(I) sites to N2. Cu(II) species can also be reacted with NO to generate Cu2+â¯(NO) adducts. The increase of carbonyl groups (CO) and carboxyl groups (COO) content also improved the chemisorption property of CuBTC. The results have shown that MOFs can serve as an ultra-efficient gas pollution adsorption material and will be more widely to be used in the field of environmental protection in the future.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Journal - Volume 358, 15 February 2019, Pages 291-298
Journal: Chemical Engineering Journal - Volume 358, 15 February 2019, Pages 291-298
نویسندگان
Xiaoli Gong, Ran Zhao, Junqi Qin, Hanmei Wang, Dong Wang,