کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
11020023 | 1717616 | 2019 | 31 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Structural and magnetic properties of Al-doped yttrium iron garnet ceramics: 57Fe internal field NMR and Mössbauer spectroscopy study
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Structural and magnetic properties of Al-doped yttrium iron garnet ceramics: 57Fe internal field NMR and Mössbauer spectroscopy study Structural and magnetic properties of Al-doped yttrium iron garnet ceramics: 57Fe internal field NMR and Mössbauer spectroscopy study](/preview/png/11020023.png)
چکیده انگلیسی
The structural and magnetic properties of Al substituted yttrium-iron garnet (Y3AlxFe5-xO12, xâ¯=â¯0, 0.1, 0.2, 0.3, 0.4, 0.6, 0.8, 1.0, 1.2, 1.4, 1.6 and 1.8) ceramic powders synthesized using solution combustion method were investigated. Post combustion, the samples were calcination at 1045â¯Â°C for 6â¯h and subsequently at 1200â¯Â°C for 6â¯h to obtain phase-pure garnets. X-ray diffraction (XRD) results confirm the formation of garnets with Ia3¯d structure. The occupancy of Y3+ ions in the dodecahedral site and the distribution of Al3+ and Fe3+ ions in the tetrahedral and octahedral sites in the bcc structure of the garnet were confirmed by Rietveld refinement of XRD patterns, Mössbauer spectroscopy and 57Fe internal field NMR spectroscopy. For low Al content, Al3+ ions have preference to occupy tetrahedral (Td) sites than the octahedral (Oh) sites. At higher Al content the distribution of Al tends towards a ratio of 3:2â¯at the tetrahedral:octahedral site. Increase in Al doping results in the decrease in the lattice parameter due to smaller size of Al3+ as compared to Fe3+ ion. All the studied samples show coral-network-like surface morphology. The saturation magnetization (MS) values decrease from â¼26.94 emu/g toâ¯â¼â¯0.17 emu/g with increase in Al content from 0.0 to 1.8. Further addition of Al makes the sample paramagnetic at RT. Substitution of non-magnetic Al3+ reduces the saturation magnetization rapidly due to the decrease in the superexchange interaction in the crystal.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 773, 30 January 2019, Pages 612-622
Journal: Journal of Alloys and Compounds - Volume 773, 30 January 2019, Pages 612-622
نویسندگان
Laxmi Narayan Mahour, M. Manjunatha, Harish Kumar Choudhary, Rajeev Kumar, A.V. Anupama, R. Damle, K.P. Ramesh, Balaram Sahoo,