کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
11027042 | 1666329 | 2018 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
A pH-responsive fragrance release system based on pseudopeptide polymeric micelles
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Controlled release of spices has always been an important subject in the fragrance and flavor industry. In this work, a kind of amphiphilic poly(2-oxazoline)s with pendant Schiff base residues in the hydrophobic segment was designed and synthesized as a potential delivery system for the pH-sensitive release of aldehyde/ketone fragrances in applications of functional perfumery. The aldehyde contents of 0.65-1.74â¯mmol/g were reached for polymer-fragrance conjugates. Upon direct dissolution in water, polymers self-assembled into micelle-type aggregates with hydrodynamic diameters ranging from 55 to 250â¯nm. The release kinetic experiments showed that the aroma-carrying nanoparticles exhibited improved stability toward hydrolysis compared to the corresponding non-micellar system. At acidic pH, the imine linkages in the polymers were gradually hydrolyzed and an increasing amount of the aldehyde was released over time. Furthermore, the pseudopeptide pro-fragrances displayed a high affinity to the cotton surface due to the presence of tertiary amide backbones and protonated amino groups in the polymeric matrices.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Reactive and Functional Polymers - Volume 132, November 2018, Pages 138-144
Journal: Reactive and Functional Polymers - Volume 132, November 2018, Pages 138-144
نویسندگان
Yuxi Liu, Keyuan Liu, Mengna Zhao, Sihang Wang, Zhuxian Zhou, Youqing Shen, Liming Jiang,