کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
11027992 | 1666142 | 2018 | 34 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Preparation of highly purity Tetrabutyl Ammonium Hydroxide using a novel method of Electro-Electrodialysis: The study on mass transfer process and influencing factors
ترجمه فارسی عنوان
آماده سازی بسیار خلوص تترابوتیل آمونیوم هیدروکسید با استفاده از روش جدید الکترو الکترویدیلیز: مطالعه بر روی فرآیند انتقال جرم و عوامل موثر بر آن
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کلمات کلیدی
هیدروکسید تترابوتیل آمونیوم، الکترو دی دیالیز، الکترولیت قلیایی، عوامل تاثیرگذار،
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
تصفیه و جداسازی
چکیده انگلیسی
Electro-Electrodialysis (EED) as a novel technology would effectively enable the preparation of Tetrabutyl Ammonium Hydroxide (TBAOH) from Tetrabutyl Ammonium Bromide (TBABr). In this work, NaOH and NH3·H2O of alkaline electrolyte were selected as anode solution to reduce the operating voltage, lower the cost and prevent the generation of bromine (Br2). The influencing factors of the current density, initial TBABr concentration, and electrolyte of the anode chamber were optimized by a triple-chambered EED stack, and also ion fluxes during the EED process were theoretically studied via an establishing mathematical model. The experimental results showed that under conditions of the optimum current density of 200â¯A/m2, initial TBABr concentration of 0.8â¯mol/L, and alkaline anolyte of 20â¯wt% NaOH, Br- content at a TBAOH concentration of 20â¯wt% was 8.5â¯ppm with the energy consumption of 1.86â¯kWâ¯h/kg and cost of 0.84 $/kg. Subsequently, continuous pilot experiments indicated that this proposed approach was promising for the efficient synthesis of TBAOH via direct splitting its halide, and further deployed at a commercial scale for the industry.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Membrane Science - Volume 567, 1 December 2018, Pages 281-289
Journal: Journal of Membrane Science - Volume 567, 1 December 2018, Pages 281-289
نویسندگان
Zhiwei Miao, Fubin Pei, Zhuangwei Liu, Zhen Zhang, Rujun Yu, Ransheng Liu,