Adsorption desulfurization performance and adsorption-diffusion study of B2O3 modified Ag-CeOx/TiO2-SiO2

The kinetics of adsorption desulfurization of model diesel fuel was investigated to provide guiding significance for the prediction of breakthrough curves of fixed-bed adsorption columns. The batch kinetic experiment modeled by HSDM model indicates that surface diffusion controls the main rate. The surface diffusion coefficient Ds determined by batch adsorption experiments is independent of operation conditions, which can be used to directly predict the breakthrough behavior in fixed bed adsorption. The modified HSDM model is proposed to describe the breakthrough behavior. Results indicate that the breakthrough time is affected by bed height, flowrate and influent concentration.