کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1213252 | 966873 | 2011 | 8 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Preparation of high purity biphenyl cyclooctene lignans from Schisandra extract by ion exchange resin catalytic transformation combined with macroporous resin separation Preparation of high purity biphenyl cyclooctene lignans from Schisandra extract by ion exchange resin catalytic transformation combined with macroporous resin separation](/preview/png/1213252.png)
In this study, ester-bond biphenyl cyclooctene lignans were efficiently hydrolytically degraded into free biphenyl cyclooctene lignans by ion exchange resin transformation and simultaneous removal of impurities by macroporous resin. The OH-type strongly basic anion exchange resin 201 × 7 was the best one, and the dynamic hydrolysis efficiency was 146.7 ± 5.0%. HPD5000 macroporous resin, which offered higher adsorption and desorption capacities and faster adsorption than other resins. The purity of free biphenyl cyclooctene lignans in the product increased from 5.14 ± 0.24% to 79.67 ± 0.0.67%. After dynamic catalytic transformation by 201 × 7 resin combined with purification of HPD5000 resin, the yield and the purity of free biphenyl cyclooctene lignans in the product were 132.1 ± 4.7% and 80.91 ± 3.53%, respectively.
► Analysis of four kinds of biphenyl cyclooctene lignans by LC–ESI-MS simultaneously.
► Hydrolysis ester-bound lignans by ion exchange resin instead of inorganic catalyst.
► The adsorption isotherm analysis by Langmuir and Freundlich model simultaneously.
Journal: Journal of Chromatography B - Volume 879, Issue 30, 15 November 2011, Pages 3444–3451