کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1229254 | 1495232 | 2015 | 8 صفحه PDF | دانلود رایگان |
• XRD, PAS, Raman and EPR studies to characterize titania.
• Presence of both rutile (91%) and anatase (9%) phases.
• PAS spectrum showed the presence of V4+, Cr3+, Mn4+ and Fe3+ species.
• EPR studies revealed the presence of V4+(d1), Cr3+(d3), Mn4+(d3) and Fe3+(d5) at Ti4+ sites.
A titania mineral (obtained from East coast, Orissa, India) was investigated by X-ray diffraction (XRD), photoacoustic spectroscopy (PAS), Raman and Electron Paramagnetic Resonance (EPR) studies. XRD studies indicated the presence of rutile (91%) and anatase (9%) phases in the mineral. Raman investigation supported this information. Both rutile and anatase phases have tetragonal structure (rutile: space group P42/mnm, a = 4.5946(1) Å, c = 2.9597(1) Å, V = 62.48(1) (Å)3, Z = 2; anatase: space group I41/amd, 3.7848(2) Å, 9.5098(11) Å, V = 136.22(2) (Å)3, Z = 4). The deconvoluted PAS spectrum showed nine peaks around 335, 370, 415,485, 555, 605, 659, 690,730 and 785 nm and according to the ligand field theory, these peaks were attributed to the presence of V4+, Cr3+, Mn4+ and Fe3+ species. EPR studies revealed the presence of transition metal ions V4+(d1), Cr3+(d3), Mn4+(d3) and Fe3+(d5) at Ti4+ sites. The EPR spectra are characterized by very large crystal filed splitting (D term) and orthorhombic distortion term (E term) for multiple electron system (s > 1) suggesting that the transition metal ions substitute the Ti4+ in the lattice which is situated in distorted octahedral coordination of oxygen. The possible reasons for observation of unusually large D and E term in the EPR spectra of transition metal ions (S = 3/2 and 5/2) are discussed.
EPR spectra of titania mineral at room temperature (A) as it is (containing microcrystals) and (B) recorded after grinding it for 30 min (polycrystalline samples).Figure optionsDownload as PowerPoint slide
Journal: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy - Volume 137, 25 February 2015, Pages 363–370