Synthesis, crystal growth and physiochemical characterization of organic NLO crystal: L-ornithinium dipicrate (LODP)

• Organic NLO crystals of L-ornithinium dipicrate were grown by slow evaporation.
• Thermal studies show the compound is stable up to 210 °C.
• Powder SHG efficiency was 14.57 greater than that of standard KDP.

L-ornithinium dipicrate (LODP) has been synthesized and good quality single crystals were grown by slow evaporation method at room temperature. Single crystal XRD confirms that the grown crystal belongs to the monoclinic system with the noncentrosymmetric space group P21. Powder X-ray diffraction study confirms the crystalline nature of the compound. FTIR spectral analysis confirms the functional group in the synthesized compound. Thermogravimetric and differential thermal analyses reveal the thermal stability of the crystal. The optical absorption spectrum shows the absence of absorption between 475 nm and 800 nm. The dielectric measurements were carried out to estimate the dielectric parameters of the grown crystal in the frequency range from 50 Hz to 5 MHz at various temperatures. The second harmonic property has been investigated by Kurtz–Perry powder technique. The relative SHG efficiency of LODP is found to be 14.57 times greater than that of the reference material KDP.

Figure optionsDownload as PowerPoint slide