کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1232804 | 1495275 | 2012 | 5 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Synthesis and photophysical properties of metallophthalocyanines substituted with a benzofuran based fluoroprobe Synthesis and photophysical properties of metallophthalocyanines substituted with a benzofuran based fluoroprobe](/preview/png/1232804.png)
The synthesis, characterization and photophysical properties of the tetra- {6-(-benzofuran-2-carboxylate)-hexylthio} substituted copper(II), cobalt(II), manganese(III) and zinc (II) phthalocyanines, {M[Pc(β-S(CH2)6OCOBz-Furan)4], which were derived from 6-(3,4-dicyanophenylthio)-hexyl-2-benzofuranate (BzF) (1–4) are reported for the first time. The new compounds have been synthesized and fully characterized by elemental analysis, FTIR, UV–vis, 1H- and 13C NMR, MS (Maldi-TOF). In this work, we also report the effects of peripherally bound BzF substituent on the photophysical properties of metallo phthalocyanine derivatives. The effects of changing the central metal ions on quantum yield are discussed. It was found that the substitution of BzF groups on the framework of phthalocyanines diminished the fluorescence quantum yield of these complexes depending on paramagnetic behavior of central metal atoms. In addition, central metal atoms like Co and Cu also caused to decrease in quantum yield of phthalocyanine backbone.
The synthesis, characterization and photophysical properties of the tetra-{6-(-benzofuran-2-carboxylate)-hexylthio} substituted copper(II), cobalt(II), manganese(III) and zinc (II) phthalocyanines (1–4), {M[Pc(β-S(CH2)6OCOBz-Furan)4], which was derivated from 6-(3,4-dicyanophenylthio)-hexyl-2-benzofuranate (BzF) are reported for the first time. In this work, we also report on the effects of peripheral BzF substituents on the photophysical parameters of metallo phthalocyanine derivatives. The effects of changing the central ions on quantum yield are discussed.Figure optionsDownload as PowerPoint slideHighlight
► Synthesis and characterization of metallophthalocyanines substituted with a benzofuran based fluoroprobe.
► Elucidation of photophysical properties of new compounds in THF solution.
► Central metal atom effect on fluorescence emission.
Journal: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy - Volume 93, July 2012, Pages 379–383