Spectroscopic and structural properties of N-(acetamide) morpholinium bromide

A new crystal of N-(acetamide) morpholinium (NAM) bromide has been prepared in methanol at room temperature and characterized by single crystal X-ray analysis, elemental analysis, GS-MS, FTIR, NMR(1H,13C, DEPTH and HETCOR). The N-(acetamide) morpholinium crystallizes in the orthorhombic crystal system, Pnma with unit cell a = 12.798(9) Å, b = 7.222(5) Å, c = 9.244(5) Å, β = 90.00, V = 854.4(9) Å3, Z = 4. The X-ray structure determination revealed that there are strong inner and intermolecular hydrogen bonds in the crystal.

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► N-(acetamide) morpholinium bromide was prepared as a single crystal.
► The spectroscopic methods FTIR, NMR (1H, 13C, HEDCOR and DEPT), UV–vis, MS were applied for the identification as well as elemental analysis and X-ray diffraction.
► Two dimensional NMR analysis was also applied for the structural analysis.
► Morpholine derivatives can find applications in many fields of industry as well as pharmaceutical industry.