کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1234062 | 968821 | 2010 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Studies on the synthesis, spectra, catalytic and antibacterial activities of binuclear ruthenium(II) complexes
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
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چکیده انگلیسی
A new series of stable binuclear ruthenium(II) carbonyl complexes of the general formula [{RuX(CO)(EPh3)2}2L] (where XÂ =Â H or Cl; EÂ =Â P or As and LÂ =Â dibasic tetradentate diacetyl resorcinol (H2-DAR)) have been synthesised by reacting ruthenium(II) starting complexes [RuHX(CO)(EPh3)3] (where XÂ =Â H or Cl; EÂ =Â P or As) and 4,6-diacetylresorcinol (H2-DAR) ligand in benzene medium. The structure of the new binuclear ruthenium(II) carbonyl complexes was established using elemental analysis, spectra (FT-IR, UV-vis and 1H NMR), electrochemical and thermal studies. In these reactions, the 4,6-diacetylresorcinol (H2-DAR) ligand behaves as a binegative tetradentate chelating ligand coordinating through O,O atoms of both the carbonyl and phenolic C-O groups by replacing a molecule of PPh3/AsPh3 and a hydride ion from the starting complexes. Further, all these complexes were also employed as new catalysts for the oxidation of primary and secondary alcohols in the presence of N-methylmorpholine-N-oxide (NMO) as a more viable co-oxidant. The free ligand and their metal complexes have also been screened for their antibacterial activity against the growth of gram +ve and gram âve bacterial cultures.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy - Volume 77, Issue 1, 15 September 2010, Pages 258-263
Journal: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy - Volume 77, Issue 1, 15 September 2010, Pages 258-263
نویسندگان
P. Krishnamoorthy, P. Sathyadevi, K. Deepa, N. Dharmaraj,