کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1234687 | 1495279 | 2012 | 4 صفحه PDF | دانلود رایگان |

The reactions of [M(CO)6], M = Cr, Mo, W with 2,6-diaminopyridine (dap) in ethanol was carried out under sun light and microwave irradiation routes of synthesis and compared with the traditional thermal reflux method. All routes resulted in the formation of the binuclear oxo complexes with the general formulas [M2(O)4(dap)2]. The prepared complexes were characterized using elemental analysis, IR, 1HNMR, mass spectrometry and magnetic measurement. The biological activity of dap and its complexes as antibacterial and antifungal reagents have been screened.
The reactions of [M(CO)6], M = Cr, Mo, W, with 2,6-diaminopyridine (dap) in ethanol was carried out under sun light and microwave irradiation routes of synthesis and compared with the traditional thermal reflux method. All routes resulted in the formation of the binuclear oxo complexes with the general formulas [M2(O)4(dap)2]. The prepared complexes were characterized using elemental analysis, IR, 1HNMR, mass spectrometry and magnetic measurement. The biological activity of dap and its complexes as antibacterial and antifungal reagents have been screened.Figure optionsDownload as PowerPoint slideHighlights
► The reactions of [M(CO)6], M = Cr, Mo or W with 2,6-diaminopyridine using sun light and microwave irradiation and the traditional reflux route.
► The binuclear oxo complexes with the general formulas [M2(O)4(dap)2]. Also, the reaction of [W(CO)6] with (dap) gave [W2(O)4(dap)2].
► The prepared complexes were characterized using elemental analysis, IR, 1HNMR, mass spectrometry and magnetic measurement.
► The biological activity of dap and its complexes as antibacterial and antifungal reagents have been screened.
Journal: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy - Volume 89, April 2012, Pages 329–332