کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1236531 | 968870 | 2011 | 4 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: A novel fluoride ion colorimetric chemosensor based on coumarin A novel fluoride ion colorimetric chemosensor based on coumarin](/preview/png/1236531.png)
A novel visible colorimetric sensor (L1) with high selectivity for fluoride ion based on coumarin has been synthesized by a simple modification of our earlier report. The chemosensor L1 shows an obvious color change from yellow to blue upon addition of fluoride ion with a large red shift of 145 nm in acetonitrile, and without interference of other anions such as Cl−, Br−, I−, NO3−, H2PO4−, HSO4−, and AcO−. The investigation of 1H NMR spectrum titration indicates the proposed mechanism is that F− first establishes a hydrogen bonding interaction with L1, and then the formation of [F–H–F]− induces deprotonation.
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► We report a novel visible colorimetric chemosensor L1 based on our previous works.
► L1 shows an obvious color change from yellow to blue upon addition of fluoride ion.
► L1 exhibits highly selective recognition of fluoride ion via the N–H deprotonation.
Journal: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy - Volume 79, Issue 5, September 2011, Pages 1352–1355