کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1236950 | 968880 | 2010 | 5 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: NMR and theoretical study on interactions between diperoxovanadate complex and pyrazole-like ligands NMR and theoretical study on interactions between diperoxovanadate complex and pyrazole-like ligands](/preview/png/1236950.png)
To understand the effects of pyrazole substitution on reaction equilibrium, the interactions between a series of pyrazole-like ligands and [OV(O2)2(D2O)]−/[OV(O2)2(HOD)]− were explored by using multinuclear (1H, 13C, and 51V) magnetic resonance, HSQC, and variable temperature NMR in 0.15 mol/L NaCl ionic medium mimicking physiological conditions. These results show that the relative reactivities among the pyrazole-like ligands are 3-methyl-1H-pyrazole ≈ 4-methyl-1H-pyrazole ≈ 1H-pyrazole > 1-methyl-1H-pyrazole. As a result, the main factor which affects the reaction equilibrium is the steric effect instead of the electronic effect of the methyl group of these ligands. A pair of isomers has been formed resulting from the coordination of 3-methyl-1H-pyrazole and a vanadium complex, which is attributed to different types of coordination between the vanadium atom and the ligands. Thus, the competitive coordination leads to the formation of a series of six-coordinate peroxovanadate species [OV(O2)2L]− (L, pyrazole-like ligands). Moreover, the results of density functional calculations provided a reasonable explanation on the relative reactivity of the pyrazole-like ligands as well as the important role of solvation in these reactions.
Journal: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy - Volume 75, Issue 3, March 2010, Pages 1095–1099