Synthesis, growth, structural, spectroscopic and optical studies of a new semiorganic nonlinear optical crystal: l-Valine hydrochloride

Single crystals of a new semiorganic nonlinear optical (NLO) material, l-valine hydrochloride (LVHCl), having dimensions up to 20 mm × 6 mm × 4 mm have been grown by slow evaporation solution growth technique. Single crystal X-ray diffraction studies confirm that the grown crystal belongs to the monoclinic system. The functional groups presented in the crystal were confirmed by Fourier transform infrared (FTIR) technique. Optical transmission spectrum shows very low absorption in the entire visible region. Differential thermal and thermogravimetric analyses confirmed that the crystal is stable up to 211 °C. The powder second harmonic generation (SHG) efficiency of LVHCl is 1.7 times efficient as potassium dihydrogen phosphate (KDP).