کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1237930 968913 2007 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Effects of the solvent and temperature on the 2:1 catechol–Al(III)-complex
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
Effects of the solvent and temperature on the 2:1 catechol–Al(III)-complex
چکیده انگلیسی

The influence of temperature and solvent effects on the stability of the complex formed by two molecules of 1,2-dihydroxybenzene and one molecule of AlCl3 were experimentally and theoretically studied, by means of UV spectroscopic methods and Density Functional Theory methods. The changes of the stability constant with the temperature were analyzed using the van’t Hoff equation, while the variations with the permittivity of the reaction medium were explained with an equation proposed by us. The experimental and theoretical data obtained allowed proving that the increase in the hydrogen-bond donor ability of the solvents favors a higher thermodynamic stability of the reactants with respect to the complex and, therefore a decrease in the corresponding stability constant. The non-planar structure proposed for the 2:1 ligand–metal complex is coherent with the small batochromic shift experimentally observed. In the complex molecule, the planes containing the phenyl rings are tilted by approximately 89° with each other. It was concluded that the complexation reaction is an endothermic process in which the solvent–solute interactions play an essential role.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy - Volume 68, Issue 2, October 2007, Pages 387–393
نویسندگان
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