کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1252165 1496329 2010 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Microscopic structure of heterogeneous lipid-based formulations revealed by 13C high-resolution solid-state and 1H PFG NMR methods
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Microscopic structure of heterogeneous lipid-based formulations revealed by 13C high-resolution solid-state and 1H PFG NMR methods
چکیده انگلیسی
Lipid-based formulations such as lip glosses that are very alike on the base of their components may have significant differences in their expected macroscopic properties as cosmetics. To differentiate such formulations, high-resolution 13C NMR was performed under magic angle spinning to investigate the properties at both molecular and microscopic levels. Temperature studies were carried out and no polymorphism in the solid domains could be evidenced after the thermal treatment performed for obtaining the commercial lip glosses. 13C NMR spectra also showed that some waxes remain partially solubilized in the oils of formulations. The microscopic structure of the wax-oil liquid domains was worked out on the basis of restricted diffusion properties obtained with proton pulsed-field gradient NMR. Changing a single wax component, in two identical formulations, yields significant morphological differences. In the first one the liquid phase appears as a continuum whereas in the second one, the liquid phase is fractionated into micrometric droplets.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemistry and Physics of Lipids - Volume 163, Issue 3, March 2010, Pages 309-317
نویسندگان
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