کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1271127 | 1497552 | 2012 | 6 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Microstructural modification of the anode/electrolyte interface of SOEC for hydrogen production Microstructural modification of the anode/electrolyte interface of SOEC for hydrogen production](/preview/png/1271127.png)
The microstructure of the anode/electrolyte interface is one of key factors to affect the hydrogen production performance of solid oxide electrolysis cells (SOECs). In this paper, a novel interfacial modification method was developed to enhance the active electrode area and the electrolysis performance via preparing a porous YSZ layer on the surface of the dense electrolyte. The effects of YSZ electrolyte pre-sintering temperature, the thickness of dense YSZ electrolyte film and preparation of porous YSZ on the microscopic morphology and the performance of single button cells were investigated. After optimization, a 9 μm porous YSZ layer was successfully prepared on the surface of a 4 μm dense YSZ electrolyte film with an OCV of 1.072 V at the temperature of 850 °C. The results of electrochemical tests showed that the current densities could elevate from −0.681 A cm−2 to −1.118 A cm−2 when electrolyzed at 1.5 V under SOEC mode after microstructural modification.
► Prepared a porous YSZ layer on the surface of the dense electrolyte.
► The thickness of dense YSZ electrolyte layer reduced to 4 μm.
► The current increased from −0.681 A cm−2 to −1.118 A cm−2 at 1.50 V.
Journal: International Journal of Hydrogen Energy - Volume 37, Issue 17, September 2012, Pages 12833–12838