کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1271972 | 1497573 | 2011 | 6 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Synthesis and characterization of terbium doped barium cerates as a proton conducting SOFC electrolyte Synthesis and characterization of terbium doped barium cerates as a proton conducting SOFC electrolyte](/preview/png/1271972.png)
A novel proton conductor, BaCe0.95Tb0.05O3−a (BCTb) perovskite was synthesized via the EDTA-citrate acid complexing method, followed by high temperature calcination. The properties of the powders were characterized by thermo gravimetric-differential thermal analysis (TG-DTA), X-ray diffraction (XRD), Scanning electron microscopy (SEM) and the conductivity measurement using the 4-probe method. In order to obtain the pure perovskite structure, the calcination temperature was elevated at 1000 °C or greater. The electrical conductivities of the BCTb perovskite mainly result from protons and are 6.51 × 10−3−2.0 × 10−2 S cm−1 in the temperature range of 600–850 °C with the activation energy of 41.95 kJ mol−1. A Ni-BCTb∣BCTb∣LSCF(La0.6Sr0.4Co0.2Fe0.8O3-α)-BCTb fuel cell was subsequently fabricated via a co-pressing/co-sintering method, followed by slurry-coating of the cathode. With 50 mL min−1 pure hydrogen as fuel and the ambient air as oxidant, the maximum output of the fuel cell has reached to 753 mW cm−2 at 700 °C. The results demonstrate that BCTb perovskite may be a promising electrolyte for the proton-conducting solid oxide fuel cells (PC-SOFCs) after its chemical stability is improved significantly.
► A proton conductor, BaCe0.95Tb0.05O3−a (BCTb) perovskite is synthesized.
► The electrical conductivities are 6.51 × 10−3−2.0 × 10−2 S cm−1 at 600−850 °C
► A Ni-BCTb∣BCTb∣LSCF-BCTb fuel cell shows a maximum output 753 mW cm−2 at 700 °C.
Journal: International Journal of Hydrogen Energy - Volume 36, Issue 20, October 2011, Pages 13067–13072