کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1272582 | 1497596 | 2010 | 5 صفحه PDF | دانلود رایگان |
The synthesis, characterization and optimization of RuxSey catalyst loading as a cathode electrode for a single polymer electrolyte membrane fuel cell, PEMFC were investigated. RuxSey catalyst was synthesized via a decarbonylation of Ru3(CO)12 and elemental selenium in 1,6-hexanediol under refluxing conditions for 2 h. The powder electrocatalyst was characterized by scanning electron microscopy (SEM), atomic force microscopy (AFM), and examined for the oxygen reduction reaction (ORR) in 0.5M H2SO4 by rotating disk electrode (RDE) and in membrane-electrode assemblies, MEAs for a single PEMFC. Results indicate the formation of agglomerates of crystalline particles with nanometric size embedded in an amorphous phase. The catalyst exhibited high current density and lower overpotential for the ORR compared to that of Rux cluster catalyst. Dispersed RuxSey catalyst loading on Vulcan carbon was optimized as a cathode electrode by performance testing in a single H2–O2 fuel cell.
Journal: International Journal of Hydrogen Energy - Volume 35, Issue 21, November 2010, Pages 12115–12119