کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1272777 | 1497603 | 2010 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
A study of catalytic hydrolysis of concentrated ammonia borane solutions
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Ruthenium catalyzed ammonia borane (AB) hydrolysis using aqueous solutions in the range of 5–25 wt% were experimentally studied. The experimental apparatus also included a means for gaseous ammonia sequestration. In addition, the effects of aging on reaction rates and total H2 conversion were investigated using AB solutions that were stored in a limited-air environment for a maximum of 67 days. The present work provides data on total H2 conversion, chemical kinetics, solution density, pH value, byproduct solubility, ammonia generation, and long-term storage stability of concentrated aqueous AB solutions.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 35, Issue 14, July 2010, Pages 7350–7356
Journal: International Journal of Hydrogen Energy - Volume 35, Issue 14, July 2010, Pages 7350–7356
نویسندگان
Alan Brockman, Yuan Zheng, Jay Gore,