کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1272923 | 1497604 | 2010 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Effect of polyoxometalate amount deposited on Pt/C electrocatalysts for CO tolerant electrooxidation of H2 in polymer electrolyte fuel cells
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Effect of polyoxometalate amount deposited on Pt/C electrocatalysts for CO tolerant electrooxidation of H2 in polymer electrolyte fuel cells Effect of polyoxometalate amount deposited on Pt/C electrocatalysts for CO tolerant electrooxidation of H2 in polymer electrolyte fuel cells](/preview/png/1272923.png)
چکیده انگلیسی
Polyoxometalate-deposited Pt/C electrocatalysts are prepared by impregnation with various amounts of polyoxometalate (POM) anions (from 2 to 16.7 wt.% PMo12O403-) on the Pt/C catalyst. The prepared electrocatalysts show a high CO electrooxidation performance over a half-cell system for CO stripping voltammetry, and CO tolerant electrooxidation of H2 is further demonstrated over a proton exchange membrane fuel cell by using CO-containing H2 gas feeds (0, 10, 50, and 100Â ppm CO in H2). In the CO stripping voltammograms, the onset and peak potentials for the CO oxidation appear to decrease as the POM deposition is increased, indicating that the electrooxidation of CO undergoes more efficiently on the catalyst surface with the deposited POMs on the Pt/C catalysts. In the single fuel cell tests with the CO-containing H2 gases, the higher current density is also generated with the larger amounts of deposited POMs on the Pt/C catalysts. Importantly, the charge transfer resistance Rp appears to decrease monotonically with the POM amounts, which was measured by electrochemical impedance spectroscopy. Physico-chemical characterizations with electrocatalytic analyses show that the deposited POMs hardly affect the active phase of Pt catalyst itself but can help the electrooxidation of H2 by efficiently oxidizing CO to prevent the Pt catalyst from poisoning. Consequently, this POM-deposited Pt/C catalyst can serve as a promising CO tolerant anode catalyst for the polymer electrolyte fuel cells that are operated with hydrocarbons-reformed H2 fuel gases.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 35, Issue 13, July 2010, Pages 6853-6862
Journal: International Journal of Hydrogen Energy - Volume 35, Issue 13, July 2010, Pages 6853-6862
نویسندگان
Sung Mook Choi, Min Ho Seo, Hyung Ju Kim, Eun Ja Lim, Won Bae Kim,