کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1273758 | 1497530 | 2013 | 6 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Synthesis of mono-disperse CoFe alloy nanoparticles with high activity toward NaBH4 hydrolysis Synthesis of mono-disperse CoFe alloy nanoparticles with high activity toward NaBH4 hydrolysis](/preview/png/1273758.png)
• CoFe nanoparticles are synthesized with cheap precursors and removable surfactant.
• The particle size of CoFe nanoparticles are tightly distributed.
• The CoFe nanoparticles show high activity toward NaBH4 hydrolysis.
Traditionally, the synthesis of CoFe nanoparticles with tunable particle sizes and narrow particle size-distributions is accomplished via the use of expensive and air sensitive precursors and strong non-polar capping agents. Such strong capping agents can be difficult to remove from the nanoparticles and thus render them catalytically inactive. We report a novel solution-based methodology to synthesize CoFe alloy nanoparticles with narrow size-distributions using a combination of robust and inexpensive metal precursors and an easily removable polar capping agent. High resolution transmission electron microscope images show that the CoFe alloy nanoparticles are well crystallized, and the particle size is tunable from 9 to 24 nm while keeping a particle size standard deviation of 10%. The CoFe alloy nanoparticles show superior activity for NaBH4 hydrolysis compared with the best-known CoFe catalysts. This work represents a substantial improvement in the synthesis of transition metal nanoparticles, opening the pathway for their application to a number of technologically important catalytic applications.
Journal: International Journal of Hydrogen Energy - Volume 38, Issue 15, 20 May 2013, Pages 6436–6441