کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1274526 | 1497549 | 2012 | 5 صفحه PDF | دانلود رایگان |
We synthesized the intermetallic compound GdNi3, which has a PuNi3-type structure (space group R-3m), and investigated its P–C isotherm. The refined lattice parameters were a = 0.4993(1) nm and c = 2.4536(4) nm. In the first absorption process, two plateaus were observed, and the maximum hydrogen capacity reached 1.07 H/M. In the first desorption process, a narrow and sloping plateau was observed at approximately 0.02 MPa. After the first full desorption, 0.6 H/M of hydrogen remained in the sample. This sample showed severe peak broadening in the XRD pattern, indicating that the metal sublattice deformed from the original alloy. No plateau region was observed in the second absorption–desorption cycle.
► In the first absorption process, two plateaus were observed and the maximum hydrogen capacity reached 1.07 H/M.
► In the first desorption process, narrow and sloping plateau was observed at approximately 0.02 MPa.
► After the first full desorption, 0.6 H/M of hydrogen remained in the sample.
► The hydrogen absorption–desorption property is irreversible.
Journal: International Journal of Hydrogen Energy - Volume 37, Issue 20, October 2012, Pages 15170–15174