Interface structure and deuterium permeation properties of Er2O3/SiC multilayer film prepared by RF magnetron sputtering

• Er2O3/SiC multilayer film was prepared to improve deuterium permeation resistance.
• Multilayer film has alternative Er2O3 and SiC layers and form modulation structure.
• The PRF value of 0.3-μm Er2O3/SiC multilayer films is about 500 at 773 K.
• The interfaces increase the hydrogen trap and restrain the deuterium permeation.

Tritium permeation barrier (TPB) of Er2O3/SiC multilayer film was proposed to improve the tritium permeation resistance of 316L stainless steel. Surface and cross-section morphologies of film were observed by SEM and TEM, The Auger electron spectroscopy was used to investigate the depth profiles of Er, O, Si and C elements in Er2O3/SiC multilayer film. The chemical state of Er, O, Si and C elements were characterized by XPS. The deuterium permeation property is measured by using a quadruple mass spectrometer. The TEM cross-section microstructure and AES depth profiles shows that the multilayer film has alternative Er2O3 and SiC layers and form a modulation structure. The 0.3-μm Er2O3/SiC multilayer film on 316L stainless steel reduces permeability by a factor up to almost 500, and higher PRFs can be obtained by optimizing the coating process. It is indicated that the Er2O3/SiC multilayer film shows the huge potential in improving the tritium permeation resistance.