Electrochemical investigation of MnO2 electrode material for supercapacitors

MnO2 electrode material is synthesized by low temperature solid state reaction between KMnO4 and MnCl2. Effects of the KMnO4:MnCl2 molar ratio on the structure, morphology and electrochemical properties of the as-prepared sample were analyzed by X-ray diffraction (XRD), scanning electron microscopy (SEM) and electrochemical tests. Results showed that the obtained MnO2 is α-MnO2, the average diameter is about 0.5–1.5 μm, which are constituted of nanoparticles of 20 nm. Under 100 mA g−1, the specific capacitances of the prepared sample is 258.7, 219.6, 215.3, 198.5 and 209.5 F g−1 at the KMnO4/MnCl2 molar ratio of 3:2, 2:1, 1:1, 1:2 and 2:3, respectively. And the MnO2 sample with a KMnO4/MnCl2 molar ratio of 3:2 exhibits the best discharge capacitance and cycle performance. When the charge/discharge rate increases to 300 mA g−1, the sample still remains initial discharge capacitance of 165.3 F g−1, and the discharge capacitance is 145.9 F g−1 after 200 cycles, the capacitance retention rate is 102.4% during the 20–200th cycles. Therefore, the MnO2 sample is an excellent material for use in supercapacitors because of its large specific capacitance and good cycle performance.

► Investigations on the effect of KMnO4/MnCl2 molar ratio on the performance of MnO2.
► Novel methods for the synthesis of MnO2 material.
► Molar ratio of KMnO4/MnCl2 has a strong effect on the synthesized MnO2 product.
► The MnO2 sample is an excellent material for use in supercapacitors.