کد مقاله کد نشریه سال انتشار مقاله انگلیسی ترجمه فارسی نسخه تمام متن
1275951 1497542 2013 13 صفحه PDF سفارش دهید دانلود رایگان
عنوان انگلیسی مقاله ISI
An atomic study of hydrogen effect on the early stage oxidation of transition metal surfaces
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
سفارش ترجمه تخصصی
با تضمین قیمت و کیفیت
موضوعات مرتبط
مهندسی و علوم پایه شیمی الکتروشیمی
پیش نمایش صفحه اول مقاله
An atomic study of hydrogen effect on the early stage oxidation of transition metal surfaces
چکیده انگلیسی

Density functional theory (DFT) and tight-binding quantum chemical molecular dynamics (QCMD) have been applied to analyze the role of interstitial hydrogen in the process of oxygen adsorption to Ni (111) and Cr-doped Ni (111) surfaces and diffusion within these metal surfaces. The DFT calculations demonstrate that the fcc hollow and octahedral sites are the most favorable for hydrogen adsorption on the surface and subsurface, respectively. A clean metal surface has a slight inward relaxation in the topmost layer, whereas the metal atoms show outward relaxation (2%) due to interstitial hydrogen. The adsorption energies of oxygen and OH have decreased to 0.26 and 0.13 eV, respectively, and the metal atomic bond further extended in the range of 1–2% in order to hydrogen remained interstitial site. Hydrogen changes to a negatively charged in the interstitial site by receiving electron. The QCMD results reveal that the oxygen penetration depth increases when hydrogen occupy into interstitial octahedral site. The deeply diffused or interstitial hydrogen receives electrons from the metal. Additionally, interstitial hydrogen initiates the charge transfer and extends the metal atomic bond. The localized process weakens the metal–metal bonds and it makes the surface chemically active for further interaction. This process can help oxygen or other species to diffuse into the structure. As a result, the subsurface hydrogen accelerates the early stage of oxidation initiation.


► Interstitial hydrogen atom significantly reduces the oxygen and OH adsorption energy.
► The subsurface hydrogen assists to locally elongate the metal atomic bond.
► The oxygen penetrates deeper into the surface when hydrogen exists interstitial site.
►  Hydrogen initiates the charge transfer and extends the metal atomic bond.
► The localized process weakens the metal–metal bonds.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 38, Issue 3, 6 February 2013, Pages 1644–1656
نویسندگان
, ,
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
سفارش ترجمه تخصصی
با تضمین قیمت و کیفیت