کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1277622 1497625 2009 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Investigation of hydrogen storage capacity of multi-walled carbon nanotubes deposited with Pd or V
موضوعات مرتبط
مهندسی و علوم پایه شیمی الکتروشیمی
پیش نمایش صفحه اول مقاله
Investigation of hydrogen storage capacity of multi-walled carbon nanotubes deposited with Pd or V
چکیده انگلیسی

This work presents the synthesis and characterization of multi-walled carbon nanotubes (multi-walled CNTs) deposited with Pd or V and their hydrogen storage capacity measured by Sievert's volumetric apparatus. The CNTs were grown by the CVD method using LPG and LaNi5 as the carbon source and catalyst, respectively. Pd was impregnated on the CNTs by the reflux method with hydrogen gas as a reducing agent, while V was embedded on the CNTs by the vapor deposition method. The average metal particle size deposited on the CNTs was around 5.8 nm for Pd and 3.6 nm for V. Hydrogen adsorption experiments were performed at room temperature and at −196 °C under a hydrogen pressure of 65 bar. At −196 °C, the treated CNTs had a maximum hydrogen uptake of 1.21 wt%, while the CNTs deposited with Pd (Pd-CNTs) and CNTs deposited with V (V-CNTs) possessed lower surface areas, inducing lower hydrogen adsorption capacities of 0.37 and 0.4 wt%, respectively. For hydrogen sorption at room temperature, the CNTs decorated with the metal nanoparticles had a higher hydrogen uptake compared to the treated CNTs. Hydrogen adsorption capacity was 0.125 and 0.1 wt% for the Pd-CNTs and V-CNTs, respectively, while the hydrogen uptake of the treated CNTs was <0.01 wt%. For the second cycle, only half of the first hydrogen uptake was obtained, and this was attributed to the re-crystallization of the defect sites on the carbon substrate after the first hydrogen desorption.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 34, Issue 16, August 2009, Pages 6669–6675
نویسندگان
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