کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1278310 | 1497546 | 2012 | 11 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Deposition of Pt nanoparticles on different carbonaceous materials by using different preparation methods for PEMFC electrocatalysts Deposition of Pt nanoparticles on different carbonaceous materials by using different preparation methods for PEMFC electrocatalysts](/preview/png/1278310.png)
The objective of this study is to evaluate different methods to obtain Pt (20 wt%)/carbon electrocatalysts, in order to identify the conditions that lead to electrocatalysts with the best electrochemical performance. This paper involves the study of different methods for the deposition and reduction of H2PtCl6 on three carbon supports: Vulcan carbon, Multiwall carbon nanotubes and mesoporous carbons. The deposition–reduction methods in liquid phase were carried out with HCOOH or NaBH4 as reducing agents. Besides, the conventional impregnation was carried out by deposition of H2PtCl6 on carbon followed by a reduction with H2 at high temperature. The electrochemical performance of supported Pt catalysts prepared by reduction in liquid phase is strongly dependent on the metallic dispersion, the particle size distribution and the nature of the carbonaceous material used as a support. Results show that the deposition–reduction method using HCOOH 0.3 M at 50–60 °C and a mesoporous carbon leads to the most efficient electrocatalyst.
► The deposition–reduction technique guarantees a complete deposition of Pt on carbon.
► The reducibility degree of Pt is about 70%.
► The EASS depends on the preparation method and the nature of the support.
► Pt catalysts supported on mesoporous carbon showed the highest electroactivity.
Journal: International Journal of Hydrogen Energy - Volume 37, Issue 23, December 2012, Pages 17910–17920