کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1278962 | 1497577 | 2011 | 9 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Analysis and improvement of cyclic stability of H2 sensing properties of Pd/Mg–Ni films Analysis and improvement of cyclic stability of H2 sensing properties of Pd/Mg–Ni films](/preview/png/1278962.png)
The nominal electrical resistivity of palladium coated magnesium–nickel (Pd/Mg–Ni) films was measured by exposing the films iteratively to hydrogen (H2) at a concentration of CH2CH2 for hydrogenation and air for dehydrogenation. When a low CH2CH2 was used, the film remained in an amorphous α-phase. H atoms interacted “interstitially” with the atomic network, and the H2 detection sensitivity S was relatively stable in the cyclic test. If higher CH2CH2 values were used, the film was partially or completely transformed to an amorphous β-phase. Significant volumetric breathing occurred in the course, leading to severe roughening of the film and oxidation of the Mg–Ni layer. S became unstable. These suggestions are supported by the results of film thickness measurements, atomic force microscopy and X-ray photoelectron spectroscopy analyses. Stability of S of a Pd/Mg–Ni film can be greatly improved by either (i) operating the film in a low CH2CH2 environment to prevent substantial volume breathing, or (ii) choosing an appropriate thickness of the Pd layer to optimize both oxidation resistance and sensing response of the film sensor.
► Resistive change of the film response differently in three ranges of hydrogen concentration CH2.
► The response in an aging test using a higher CH2 for hydrogenation is more unstable.
► Two methods to improve the cyclic stability of the resistive H2 sensing properties of Pd/Mg–Ni film.
Journal: International Journal of Hydrogen Energy - Volume 36, Issue 16, August 2011, Pages 10188–10196