کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1279156 | 1645388 | 2011 | 9 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Nanoscopic Al1−xCex phases in the NaH + Al + 0.02CeCl3 system Nanoscopic Al1−xCex phases in the NaH + Al + 0.02CeCl3 system](/preview/png/1279156.png)
The NaH + Al + 0.02CeCl3 system has been studied by high-resolution X-ray synchrotron diffraction and transmission electron microscopy (TEM), after planetary milling under hydrogen and hydrogen (H) cycling. Isothermal absorption kinetics were determined at 150 °C, and compared with the NaH + Al + 0.02TiCl3 system, indicating that CeCl3 and TiCl3 are equally effective additives, with CeCl3 preferred on the basis of hydrogen storage capacity. After milling, AlCe contains 100% of the Ce. After the first H absorption, we observe two Al1−xCex phases. The first, AlCe, contains ca. 60% of the originally added Ce atoms. The AlCe phase observed after milling and H cycling is chemically disordered, with complete exchange between the Al and Ce sublattices occurring, yielding zero intensity in ordering reflections such as (100). In the absorbed state after H cycling, the remaining 40% of Ce atoms are contained in a cubic Al1−xCex phase not previously observed in the Al-Ce phase diagram. Indexing yields a primitive cubic unit cell of dimension 7.7111 Å, in space group P23. Lineshape analysis indicates the AlCe and unknown cubic Al1−xCex phases are ca. 35 nm and 30 nm in dimension respectively. High resolution TEM imaging confirms that both Al1−xCex phases are embedded on the NaAlH4 surface, and localised energy dispersive X-ray spectroscopy (EDS) indicates a ca. 2:1 Al:Ce ratio for the unknown cubic Al1−xCex phase.
► State of the art NaH + Al + 0.02CeCl3 complex hydride system for practical application.
► Combined X-ray synchrotron and TEM investigation.
► Ball milling under a reactive hydrogen atmosphere.
► Surface embedded nanoscopic Al1−xCex phases.
► Rapid hydrogenation kinetics.
Journal: International Journal of Hydrogen Energy - Volume 36, Issue 14, July 2011, Pages 8403–8411