کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1280150 | 1497598 | 2010 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Tuning of electron transfer in diiron azo-bridged complexes relevant to hydrogenases
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The possibility of using hydrogenase models based on Fe2(μ-NRN) complexes was investigated. The use of benzo-[c]-cinnoline (BC = N2C12H8) bridge allows for an unprecedented control of the electron-transfer process in diiron complexes. We were able to modify the potential gap between the two one-electron reduction steps of [Fe2(BC)(CO)6] by changing the solvent properties. The catalyst exhibits modest catalytic activity for proton reduction. However, there is a considerable opportunity for improvement considering the wide range of azo-bridged diiron described in the literature.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 35, Issue 19, October 2010, Pages 10797–10802
Journal: International Journal of Hydrogen Energy - Volume 35, Issue 19, October 2010, Pages 10797–10802
نویسندگان
Pierre-Yves Orain, Jean-François Capon, Frederic Gloaguen, Philippe Schollhammer, Jean Talarmin,