کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1280256 | 1497599 | 2010 | 5 صفحه PDF | دانلود رایگان |
Mg and Zr-based AB2 hydride composite was prepared by hydriding combustion synthesis (HCS) and the hydriding–dehydriding properties of HCS Mg–(20, 40 wt%)AB2 products were extensively examined. The dehydriding onset temperatures of the HCS Mg–20AB2 and Mg–40AB2 composites were 533 K and 493 K, respectively, which were lower than that of the MgH2. It is suggested that the well-dispersed Zr-based AB2 phase in a Mg composite prepared by HCS plays a crucial role in significantly improving its kinetic properties. Especially, the HCS Mg–20AB2 composite showed fully activated hydrogenation within the 8th cycle and reached a saturated H2 absorption capacity of 5.7 wt.% at 573 K in 10 min. In addition, the hydrogen capacity did not show any significant decrease even after 86 cycles. These results display a potential excellence of HCS processing in preparing Mg-based hydrogen storage materials.
Journal: International Journal of Hydrogen Energy - Volume 35, Issue 18, September 2010, Pages 9641–9645