کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1281114 1497624 2009 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Structural destabilisation of MgH2 obtained by heavy ion irradiation
موضوعات مرتبط
مهندسی و علوم پایه شیمی الکتروشیمی
پیش نمایش صفحه اول مقاله
Structural destabilisation of MgH2 obtained by heavy ion irradiation
چکیده انگلیسی

MgH2 powder samples have been irradiated with 120 keV Ar+8 ions with different ion fluencies ranging from 1012 to 1016 ions/cm2. Irradiation effects are estimated by SRIM calculations, and investigated experimentally using Raman spectroscopy and X-ray diffraction (XRD) analysis. The observed changes of structure and vibrational spectra are elaborated, their consequences on hydrogen bonding in MgH2 discussed, and influence on H-desorption properties investigated by Temperature Programmed Desorption (TPD) and Differential Scanning Calorimetry (DSC) techniques. It has been established that near-surface defects have a predominant influence on decreasing the H-desorption temperature. Variations of Raman, TPD and DSC spectra with irradiation conditions suggest that there are several mechanisms of dehydriding, and that they depend on defect concentration, interaction and ordering.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 34, Issue 17, September 2009, Pages 7275–7282
نویسندگان
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