کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1281195 1497636 2009 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Ten-year efforts and a no-go recommendation for sodium borohydride for on-board automotive hydrogen storage
موضوعات مرتبط
مهندسی و علوم پایه شیمی الکتروشیمی
پیش نمایش صفحه اول مقاله
Ten-year efforts and a no-go recommendation for sodium borohydride for on-board automotive hydrogen storage
چکیده انگلیسی

In the early 2000s, sodium borohydride (NaBH4) was presented as a promising hydrogen storage material with an ideal gravimetric hydrogen storage capacity of 10.8 wt%. Despite ten-year efforts in research and development, the U.S. Department of Energy (US DOE) recommended a no-go for NaBH4 for on-board automotive hydrogen storage. This is the central purpose of the present paper. The US DOE decision was based on the following observations: too low effective gravimetric hydrogen storage capacities, inefficiency of hydrolysis by-product (NaBO2) recycling, and cost. The present paper illustrates this decision on the basis of the state-of-the-art we can find throughout the open international literature. Furthermore as the decision clearly focuses automotive applications, we attempt to show that NaBH4 may have a potential for portable applications.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 34, Issue 6, March 2009, Pages 2638–2645
نویسندگان
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