کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1281930 | 1497668 | 2007 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Development of Mg-oxide-Ni hydrogen-storage alloys by reactive mechanical grinding
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Mg-oxide and Mg-oxide-Ni hydrogen storage alloys were prepared by mechanical grinding under H2 (reactive mechanical grinding). Among these alloys, Mg-(7.5wt%Fe2O3, 7.5Â wt%Ni) prepared by grinding for 4Â h with nano-structured Fe2O3 particles and Ni showed the best hydrogen storage properties. The as-milled sample absorbed 4.75Â wt% H at 593Â K under 12Â bar H2 for 60Â min. Its activation was accomplished after two hydriding-dehydriding cycles. The activated sample absorbed 4.36Â wt% H at 593Â K under 12Â bar H2 for 60Â min and desorbed 4.26Â wt% H at 593Â K under 1.0Â bar H2 for 60Â min. After hydriding-dehydriding cycling, Mg2Ni, Fe and MgO are formed. The large bar-like hydrided particles have round and expanding surfaces, suggesting that they expanded during the hydriding reaction, while the dehydrided particles exhibit contracted surfaces with wrinkles.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 32, Issue 16, November 2007, Pages 3921-3928
Journal: International Journal of Hydrogen Energy - Volume 32, Issue 16, November 2007, Pages 3921-3928
نویسندگان
MyoungYoup Song, SungNam Kwon, Daniel R. Mumm, Seong-Hyeon Hong,